Author(s): Mohammed Z. Ghadhyeb, Ali Atiyah Abid, Muhnad Dohan Abid

Email(s): Mohzg67@gmail.com

DOI: 10.52711/0974-360X.2021.00936   

Address: Mohammed Z. Ghadhyeb1*, Ali Atiyah Abid2, Muhnad Dohan Abid2
1Department of Chemistry, Faculty of Science, Kufa University, Najaf, Iraq.
2Ministry of Education, The General Directorate of Educational in Najaf Al-Ashraf, Najaf, Iraq.
*Corresponding Author

Published In:   Volume - 14,      Issue - 10,     Year - 2021


ABSTRACT:
The present study describes synthesis, characterization (UV-Vis, FT-IR, 1HNMR, CHN analysis and melting point) and biological activity of new substituted benzimidazolium salt and their N-heterocycliccarbene (NHC) respective Ag(I) and Pd(II) complexes. The benzimidazole reacted with acetamide substituents at 90oC to form variety substituted of benzimidazolium salt to yield unsymmetrically substituted salt. Silver(I) complex was synthesized from the reaction of unsymmetrical substituted benzimidazolium salt with Ag2O using in-situ deprotonation technique to give derived structures in good yield.The use of Ag(I)-NHC complex is as transfer reagents by using the transmetallation technique to prepare respective Pd(II)-NHC. The biological activity. of the formed substituted benzimidazolium salts, Ag(I) and Pd(II) complexes was estimated against some bacteria strains S. aureus. And E.coli .The Ag(I)showed good activity while their corresponding salt and Pd(II)-NHC complex show less activity.


Cite this article:
Mohammed Z. Ghadhyeb, Ali Atiyah Abid, Muhnad Dohan Abid. Bridge, N-heterocyclic Carbene Complexes with Silver (I) and Palladium (II): Synthesis and Biological Activity. Research Journal of Pharmacy and Technology 2021; 14(10):5366-0. doi: 10.52711/0974-360X.2021.00936

Cite(Electronic):
Mohammed Z. Ghadhyeb, Ali Atiyah Abid, Muhnad Dohan Abid. Bridge, N-heterocyclic Carbene Complexes with Silver (I) and Palladium (II): Synthesis and Biological Activity. Research Journal of Pharmacy and Technology 2021; 14(10):5366-0. doi: 10.52711/0974-360X.2021.00936   Available on: https://www.rjptonline.org/AbstractView.aspx?PID=2021-14-10-54


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