Author(s): Ramesh R. Pawar, Sandip B. Nahire

Email(s): nahiresandip@gmail.com

DOI: 10.5958/0974-360X.2021.00218.3   

Address: Ramesh R. Pawar, Sandip B. Nahire*
Department of Chemistry, M.S.G. College, Malegaon (M.S.) India.
*Corresponding Author

Published In:   Volume - 14,      Issue - 3,     Year - 2021


ABSTRACT:
The measurement of solubilities of malonic acid in water, methanol, ethanol, water + methanol and water + ethanol binary solvent mixtures were carried out over the entire composition range between 0 to 1 weight fraction of methanol and ethanol at (293.15, 295.15, 298.15, 300.15, 303.15, 305.15, 308.15, and 313.15) K. The experimental solubility data were correlated by using Apelblat and van’t Hoff equation. These equations provide better correlation in these measurements. DFT was carried out to correlate solubility in various solvents system. Thermodynamic parameters (?H_soln^0,? ?S?_soln^0, ??G?_soln^0, %?H, %?TS) of solution were calculated using van’t Hoff equation.


Cite this article:
Ramesh R. Pawar, Sandip B. Nahire. Investigation, Correlation and DFT study for solubility of Malonic acid in water + methanol and water + ethanol binary solvents at T = 293.15 to 313.15 K. Research J. Pharm. and Tech. 2021; 14(3):1226-1232. doi: 10.5958/0974-360X.2021.00218.3

Cite(Electronic):
Ramesh R. Pawar, Sandip B. Nahire. Investigation, Correlation and DFT study for solubility of Malonic acid in water + methanol and water + ethanol binary solvents at T = 293.15 to 313.15 K. Research J. Pharm. and Tech. 2021; 14(3):1226-1232. doi: 10.5958/0974-360X.2021.00218.3   Available on: https://www.rjptonline.org/AbstractView.aspx?PID=2021-14-3-6


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